NickelMaghrebV1, France, Analysis, bibRecord, 000331

Surface plasma functionalization of polycarbonate : Application to electroless nickel and copper plating

Identifieur interne : 000331 ( France/Analysis ); précédent : 000330; suivant : 000332

Surface plasma functionalization of polycarbonate : Application to electroless nickel and copper plating

Auteurs : M. Charbonnier [France] ; M. Romand [France] ; E. Harry [France] ; M. Alami [Maroc]

Source :

Journal of applied electrochemistry [ 0021-891X ] ; 2001.

RBID : Pascal:01-0210341

Descripteurs français

Pascal (Inist)
- Métallisation, Carbonate polymère, Traitement surface, Plasma, Chimisorption, Palladium, Dépôt par oxydoréduction, Réaction électrochimique, Nickel, Cuivre, Structure surface, Spectrométrie photoélectron, Rayon X.
Wicri :
- topic : Nickel, Cuivre.

English descriptors

KwdEn :
- Chemisorption, Copper, Electrochemical reaction, Electroless plating, Metallizing, Nickel, Palladium, Photoelectron spectrometry, Plasma, Polycarbonate, Surface structure, Surface treatment, X ray.

Abstract

Electroless metallization of polymers requires different steps including (i) the preconditioning of the surface to render it chemically reactive, (ii) the chemisorption of a catalyst (Pd) to activate the so-modified surface towards subsequent metallization, and (iii) the metallization itself. In the present work, electroless metallization was carried out on poly(carbonate) substrates, and step (i) was performed using plasma treatments in various gaseous atmospheres (NH₃, N₂, O₂). When a sufficiently high surface concentration of nitrogenated groups is grafted it is shown from X-ray photoelectron (XPS) analyses that the so-functionalized surfaces can chemisorb Pd²⁺ ions directly from a simple PdCl₂ solution. Thus, step (i) allows simplification of the conventional electroless processes commonly used up to now. Moreover, XPS analyses indicate chemical reduction of Pd²⁺ ions to Pd(0) during the more or less long initiation time before the start of metallization. This reduction is easily performed in nickel plating baths thanks to the hypophosphite reducer. On the other hand, this reduction is possible with formaldehyde, the reducer of copper plating baths, only if Sn²⁺ ions (brought by the conventional processes using SnCl₂ and PdCl₂ solutions) are present.

Affiliations:

Links toward previous steps (curation, corpus...)

to stream PascalFrancis, to step Corpus: 000417
to stream PascalFrancis, to step Curation: 000024
to stream PascalFrancis, to step Checkpoint: 000404
to stream Main, to step Merge: 000B19
to stream Main, to step Curation: 000A94
to stream Main, to step Exploration: 000A94
to stream France, to step Extraction: 000331

Links to Exploration step

Pascal:01-0210341

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Surface plasma functionalization of polycarbonate : Application to electroless nickel and copper plating</title>
<author><name sortKey="Charbonnier, M" sort="Charbonnier, M" uniqKey="Charbonnier M" first="M." last="Charbonnier">M. Charbonnier</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Sciences et Ingénierie des Surfaces, Université Claude Bernard, Lyon 1</s1>
<s2>69622 Villeurbanne</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region>
<region type="old region" nuts="2">Rhône-Alpes</region>
<settlement type="city">Villeurbanne</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Romand, M" sort="Romand, M" uniqKey="Romand M" first="M." last="Romand">M. Romand</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Sciences et Ingénierie des Surfaces, Université Claude Bernard, Lyon 1</s1>
<s2>69622 Villeurbanne</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region>
<region type="old region" nuts="2">Rhône-Alpes</region>
<settlement type="city">Villeurbanne</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Harry, E" sort="Harry, E" uniqKey="Harry E" first="E." last="Harry">E. Harry</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Sciences et Ingénierie des Surfaces, Université Claude Bernard, Lyon 1</s1>
<s2>69622 Villeurbanne</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region>
<region type="old region" nuts="2">Rhône-Alpes</region>
<settlement type="city">Villeurbanne</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Alami, M" sort="Alami, M" uniqKey="Alami M" first="M." last="Alami">M. Alami</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Ecole Nationale Supérieure des Arts et Métiers, Université Moulay Ismail</s1>
<s2>Meknès</s2>
<s3>MAR</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>Meknès</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">01-0210341</idno>
<date when="2001">2001</date>
<idno type="stanalyst">PASCAL 01-0210341 INIST</idno>
<idno type="RBID">Pascal:01-0210341</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000417</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000024</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">000404</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000404</idno>
<idno type="wicri:doubleKey">0021-891X:2001:Charbonnier M:surface:plasma:functionalization</idno>
<idno type="wicri:Area/Main/Merge">000B19</idno>
<idno type="wicri:Area/Main/Curation">000A94</idno>
<idno type="wicri:Area/Main/Exploration">000A94</idno>
<idno type="wicri:Area/France/Extraction">000331</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Surface plasma functionalization of polycarbonate : Application to electroless nickel and copper plating</title>
<author><name sortKey="Charbonnier, M" sort="Charbonnier, M" uniqKey="Charbonnier M" first="M." last="Charbonnier">M. Charbonnier</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Sciences et Ingénierie des Surfaces, Université Claude Bernard, Lyon 1</s1>
<s2>69622 Villeurbanne</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region>
<region type="old region" nuts="2">Rhône-Alpes</region>
<settlement type="city">Villeurbanne</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Romand, M" sort="Romand, M" uniqKey="Romand M" first="M." last="Romand">M. Romand</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Sciences et Ingénierie des Surfaces, Université Claude Bernard, Lyon 1</s1>
<s2>69622 Villeurbanne</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region>
<region type="old region" nuts="2">Rhône-Alpes</region>
<settlement type="city">Villeurbanne</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Harry, E" sort="Harry, E" uniqKey="Harry E" first="E." last="Harry">E. Harry</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Sciences et Ingénierie des Surfaces, Université Claude Bernard, Lyon 1</s1>
<s2>69622 Villeurbanne</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Auvergne-Rhône-Alpes</region>
<region type="old region" nuts="2">Rhône-Alpes</region>
<settlement type="city">Villeurbanne</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Alami, M" sort="Alami, M" uniqKey="Alami M" first="M." last="Alami">M. Alami</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Ecole Nationale Supérieure des Arts et Métiers, Université Moulay Ismail</s1>
<s2>Meknès</s2>
<s3>MAR</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<wicri:noRegion>Meknès</wicri:noRegion>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Journal of applied electrochemistry</title>
<title level="j" type="abbreviated">J. appl. electrochem.</title>
<idno type="ISSN">0021-891X</idno>
<imprint><date when="2001">2001</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Journal of applied electrochemistry</title>
<title level="j" type="abbreviated">J. appl. electrochem.</title>
<idno type="ISSN">0021-891X</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chemisorption</term>
<term>Copper</term>
<term>Electrochemical reaction</term>
<term>Electroless plating</term>
<term>Metallizing</term>
<term>Nickel</term>
<term>Palladium</term>
<term>Photoelectron spectrometry</term>
<term>Plasma</term>
<term>Polycarbonate</term>
<term>Surface structure</term>
<term>Surface treatment</term>
<term>X ray</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Métallisation</term>
<term>Carbonate polymère</term>
<term>Traitement surface</term>
<term>Plasma</term>
<term>Chimisorption</term>
<term>Palladium</term>
<term>Dépôt par oxydoréduction</term>
<term>Réaction électrochimique</term>
<term>Nickel</term>
<term>Cuivre</term>
<term>Structure surface</term>
<term>Spectrométrie photoélectron</term>
<term>Rayon X</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Nickel</term>
<term>Cuivre</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Electroless metallization of polymers requires different steps including (i) the preconditioning of the surface to render it chemically reactive, (ii) the chemisorption of a catalyst (Pd) to activate the so-modified surface towards subsequent metallization, and (iii) the metallization itself. In the present work, electroless metallization was carried out on poly(carbonate) substrates, and step (i) was performed using plasma treatments in various gaseous atmospheres (NH<sub>3</sub>
, N<sub>2</sub>
, O<sub>2</sub>
). When a sufficiently high surface concentration of nitrogenated groups is grafted it is shown from X-ray photoelectron (XPS) analyses that the so-functionalized surfaces can chemisorb Pd<sup>2+</sup>
 ions directly from a simple PdCl<sub>2</sub>
 solution. Thus, step (i) allows simplification of the conventional electroless processes commonly used up to now. Moreover, XPS analyses indicate chemical reduction of Pd<sup>2+</sup>
 ions to Pd(0) during the more or less long initiation time before the start of metallization. This reduction is easily performed in nickel plating baths thanks to the hypophosphite reducer. On the other hand, this reduction is possible with formaldehyde, the reducer of copper plating baths, only if Sn<sup>2+</sup>
 ions (brought by the conventional processes using SnCl<sub>2</sub>
 and PdCl<sub>2</sub>
 solutions) are present.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>Maroc</li>
</country>
<region><li>Auvergne-Rhône-Alpes</li>
<li>Rhône-Alpes</li>
</region>
<settlement><li>Villeurbanne</li>
</settlement>
</list>
<tree><country name="France"><region name="Auvergne-Rhône-Alpes"><name sortKey="Charbonnier, M" sort="Charbonnier, M" uniqKey="Charbonnier M" first="M." last="Charbonnier">M. Charbonnier</name>
</region>
<name sortKey="Harry, E" sort="Harry, E" uniqKey="Harry E" first="E." last="Harry">E. Harry</name>
<name sortKey="Romand, M" sort="Romand, M" uniqKey="Romand M" first="M." last="Romand">M. Romand</name>
</country>
<country name="Maroc"><noRegion><name sortKey="Alami, M" sort="Alami, M" uniqKey="Alami M" first="M." last="Alami">M. Alami</name>
</noRegion>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/NickelMaghrebV1/Data/France/Analysis

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000331 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/France/Analysis/biblio.hfd -nk 000331 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    NickelMaghrebV1
   |flux=    France
   |étape=   Analysis
   |type=    RBID
   |clé=     Pascal:01-0210341
   |texte=   Surface plasma functionalization of polycarbonate : Application to electroless nickel and copper plating
}}

This area was generated with Dilib version V0.6.27.
Data generation: Fri Mar 24 23:14:20 2017. Site generation: Tue Mar 5 17:03:47 2024

	Serveur d'exploration sur le nickel au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le nickel au Maghreb

Surface plasma functionalization of polycarbonate : Application to electroless nickel and copper plating

Surface plasma functionalization of polycarbonate : Application to electroless nickel and copper plating

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri